Pyrite Formation Mechanisms

Redox sensitive trace elements in pyrite including nodules are increasingly used to infer the chemical conditions of ancient oceansbut considerable uncertainty remains regarding the mechanism and timing of nodule formation

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Mechanisms of sedimentary pyrite formation Sulfur

The mechanisms of pyrite formation are reviewed Advances since 1994 in our understanding of the mechanisms and rate of pyrite formation the role of bacteria in the formation of pyrite framboid formation and incorporation of impurities into pyrite are emphasized

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Pyrite formation from FeS and H2S is mediated through

Apr 02 2019 · Pyrite is the most abundant iron−sulfur mineral in sediments Over geological times its burial controlled oxygen levels in the atmosphere and sulfate concentrations in seawater However the mechanism of pyrite formation in sediments is still being debated We show that lithotrophic microorganisms can mediate the transformation of FeS and H2S to FeS2 at ambient temperature if

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pyrite formation mechanisms

Sedimentary pyrite formation is the mechanism of pyrite formation and specifically to derive reac by no means restricted to marine coastal environments although tion rates there are still some significant gaps in our knowledge that is where most sedimentary pyrite is formed

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Mechanisms of sedimentary pyrite formation Request PDF

The mechanisms of pyrite formation are reviewed Advances since 1994 in our understanding of the mechanisms and rate of pyrite formation the role of bacteria in the formation of pyrite framboid

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PDF Mechanisms of sedimentary pyrite formation Martin

Sedimentary pyrite formation is the mechanism of pyrite formation and specifically to derive reac by no means restricted to marine coastal environments although tion rates there are still some significant gaps in our knowledge that is where most sedimentary pyrite is formed

Learn More
pyrite formation mechanisms

Sedimentary pyrite formation is the mechanism of pyrite formation and specifically to derive reac by no means restricted to marine coastal environments although tion rates there are still some significant gaps in our knowledge that is where most sedimentary pyrite is formed

Learn More
Pyrite Oxidation Kinetics How Fast does Pyrite Oxidize

Pyrite oxidation has been studied extensively in the past because of its importance in sulfide mineral separations by flotation in the generation of acid in mine waters and in leaching of pyrite The oxidation of pyrite also plays key role in supergene alteration of ore deposits the formation of acid sulfate soils etc Pyrite oxidation is generally recognized as a complicated process

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Pyriteinduced hydroxyl radical formation and its effect

Apr 04 2006 · The formation of • OH but not the formation of H 2 O 2 is inhibited when EDTA is added to the pyrite suspensions which suggests that the H 2 O 2to• OH conversion takes place in solution However more research is needed to resolve the mechanism or mechanisms

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Abiotic Pyrite Formation Produces a Large Fe Isotope

Jun 24 2011 · The iron isotope composition of sedimentary pyrite has been proposed as a potential proxy to trace microbial metabolism and the redox evolution of the oceans We demonstrate that Fe isotope fractionation accompanies abiotic pyrite formation in the absence of FeII redox change Combined fractionation factors between FeIIaq mackinawite and pyrite permit the generation of pyrite

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Pyrite formation from FeS and H2S is mediated through

the mechanism of pyrite formation in natural environments is still being debated 1 Currently two mechanisms are discussed to drive pyrite formation in sediments which both preclude dissolution of precipitated ironII monosulfide FeS to an aqueous FeS intermediate In the polysulfide pathway FeS aq is attacked by nucle

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PDF Kinetics and Mechanism of Pyrite Formation at Low

Kinetics and Mechanism of Pyrite Formation at Low Temperatures Article PDF Available in American Journal of Science 2756636652 · June 1975 with 425 Reads How we measure reads

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Pyrite Oxidation Mechanism by Oxygen in Aqueous

oxidation mechanism was proposed although it suggested the formation of an exotic FeIV O2− species which might be readily reduced in the presence of water This work aims to contribute for understanding the pyrite abiotic oxidation mechanism by oxygen in the presence of water using the DFTplanewave theoretical approach We

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The formation mechanisms of sedimentary pyrite nodules

Request PDF on ResearchGate On Jun 1 2019 Daniel Gregory and others published The formation mechanisms of sedimentary pyrite nodules determined by

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Role of pyrite in formation of hydroxyl SpringerLink

The results are consistent with earlier work which showed that the pyriteinduced • OH generation mechanism scales with pyrite surface area which strongly implies a surfacemediated mechanism Experiments were performed to evaluate any additional contribution of • OH formation from the organic carbon fraction of coal in addition to the

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Mechanisms of pyrite and marcasite formation from

Abstract The formation of pyrite and marcasite from solutions between 100 and 300°C has been examined experimentally and the solubility product for the initial precipitate upon mixing of Fe 2 and H 2 S solutions has been determined Below 300°C pyrite and marcasite form via an FeS precursor

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Replacement of pyrrhotite by pyrite and marcasite under

The pyrrhotite to Fe disulfide reaction proceeded by a dissolutionreprecipitation mechanism under all conditions Marcasite and pyrite formed under both oxic and anaerobic conditions which is inconsistent with the traditionally assumed polysulfide route for FeS2 formation oxidants required for polysulfide formation

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Coupled partitioning of Au and As into pyrite controls

The partitioning of As and Au into pyrite was studied by replacing siderite FeCO 3 by pyrite FeS 2 by reacting the Fe carbonate with H 2 Scontaining aqueous fluids under experimental conditions similar to those of CTGD formation ie 200°C fluiddominated conditions 005 m H 2 S and slightly acidic see Materials and Methods for

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The kinetics of the oxidation of pyrite by ferric ions and

The dissolution of pyrite is important in the geochemical cycling of iron and sulphur in the formation of acid mine drainage and in the extraction of metals by bacterial leaching Many researchers have studied the kinetics of dissolution and the rate of dissolution has often been found to

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Role of pyrite in formation of hydroxyl radicals in coal

Dec 19 2006 · The formation of • OH and H 2 O 2 from coal samples that contain pyrite is consistent with our previous finding that pyrite can spontaneously generate • OH and H 2 O 2 The lack of • OH and H 2 O 2 from coal samples that do not contain pyrite implies that the mechanism involves pyrite and not the organic fraction of coal

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